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QuickNotes™  

Colligative Properties, Colloids, Surfactants

  • Colligative properties of solutions – properties depending on number of particles (ions, molecules) dissolved

  • Raoult’s Law of vapor pressure lowering: vp = vpo(mol. frac. solvent)

  • Elevation of b.p. and depression of f.p. similar: DT = K(molality)

  • Use these to determine molar masses of solutes

  • V der W’s alpha: anomalous results due to ionic dissociation

  • Osmosis: flow of solvent across semipermeable membranes; example – red blood cells

  • Osmotic Pressure, PV =nRT where R is usual gas constant

  • Use osmotic pressure to determine molar masses of large molecules like proteins

  • Colloids: particles larger than ions/molecules but not large enough to settle

  • Tyndall effect: colloids scatter light

  • Soaps and surfactants: hydrophilic head and hydrophobic tail

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